Spyrale, Safety Data, Fungicides, Syngenta Crop Protection

FUNGICIDES

SAFETY DATA

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY OR UNDERTAKING
Identification of the substance or preparation
Tradename: SPYRALE
Design Code: A9424B
AGI Code: 24356/131097

Company identification
Company Syngenta Crop Protection UK Ltd
CPC4, Capital Park, Fulbourn, Cambridge CB21 5XE
Phone (01223) 883400
Fax (01223) 882195
Website www.syngenta-crop.co.uk
Emergency Phone +44 (0)1484 538444 (24h)

2. COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENTS
fenpropidin
CAS-NO.: 67306-00-7
EC-NO.: -
Concentration(%W/W): 37.7
HAZARD SYMBOL(S): Xn, N
R PHRASES(R): 20/22, 37/38, 41, 43, 50/53

difenoconazole
CAS-NO.: 119446-68-3
EC-NO.: -
Concentration(%W/W): 10
HAZARD SYMBOL(S): Xn, N
R PHRASES(R): 22, 50/53

solvent naphtha (petroleum), highly arom
CAS-NO.: 64742-94-5
EC-NO.: 265-198-5
Concentration(%W/W): 35–40
HAZARD SYMBOL(S): Xn, N
R PHRASES(R): 36/37/38.51/53, 65, 66

For the full text of the R phrases mentioned in this section, see section 16.

3. HAZARDS IDENTIFICATION
Harmful if swallowed. Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

4. FIRST AID MEASURES
General advice: Have the product container, label or Material Safety Data Sheet with you when calling the Syngenta emergency number, a Poison Control Centre or physician, or going for treatment.
Inhalation: Move to fresh air. If breathing is irregular or stopped, administer artificial respiration. Keep patient warm and at rest. Call a physician or Poison Control Centre immediately.
Skin contact: Take off all contaminated clothing immediately. Wash off immediately with plenty of water. If skin irritation persists, call a physician. Wash contaminated clothing before re-use.
Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses. Immediate medical attention is required.
Ingestion: If swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting: contains petroleum distillates and/or aromatic solvents.
Medical advice: There is no specific antidote available. Treat symptomatically. Do not induce vomiting: contains petroleum distillates and/or aromatic solvents.

5. FIRE FIGHTING MEASURES
Suitable extinguishing media
Extinguishing media – small fires: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Extinguishing media – large fires: Alcohol-resistant foam or water spray
Extinguishing media which must not be used for safety reasons: Do not use a solid water stream as it may scatter and spread fire.
Specific hazards during fire fighting: As the product contains combustible organic components, fire will produce dense black smoke containing hazardous products of combustion (see section 10). Exposure to decomposition products may be a hazard to health.
Special protective equipment for fire fighters: In the event of fire, wear full protective clothing and self-contained breathing apparatus.
Further information: Do not allow run-off from fire fighting to enter drains or water courses. Cool closed containers exposed to fire with water spray.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Refer to protective measures listed in sections 7 and 8.
Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system.
Methods for cleaning up: Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13).
Additional advice: If the product contaminates rivers and lakes or drains inform respective authorities.

7. HANDLING AND STORAGE
HANDLING
Advice on safe handling: No special technical protective measures required. No special handling advice required. Avoid contact with skin and eyes. When using do not eat, drink or smoke. For personal protection see section 8.

STORAGE
Requirements for storage areas and containers: No special storage conditions required. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep away from food, drink and animal feed.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components: difenoconazole
Exposure limit(s): 8 mg/m3
Value type: 8 h TWA
Source: SYNGENTA

Components: solvent naphtha (petroleum), highly arom.
Exposure limit(s): 15 ppm 100 mg/m3
Value type: 8 h TWA
Source: SUPPLIER

Components: fenpropidin
Exposure limit(s): 5 mg/m3
Value type: 8 h TWA
Source: SYNGENTA

ENGINEERING MEASURES
Containment and/or segregation is the most reliable technical protection measure if exposure cannot be eliminated. The extent of these protection measures depends on the actual risks in use. If airborne mists or vapours are generated, use local exhaust ventilation controls. Assess exposure and use any additional measures to keep airborne levels below any relevant exposure limit. Where necessary, seek additional occupational hygiene advice.

PERSONAL PROTECTIVE EQUIPMENT
When using this product refer to the label for details. In all other cases, use the following Personal Protective Equipment:
Protective measures: The use of technical measures should always have priority over the use of personal protective equipment. When selecting personal protective equipment, seek appropriate professional advice. Personal protective equipment should be certified to appropriate standards.
Respiratory protection: A combination gas, vapour and particulate respirator may be necessary until effective technical measures are installed. Protection provided by air-purifying respirators is limited. Use a self-contained breathing apparatus in cases of emergency spills, when exposure levels are unknown, or under any circumstances where air-purifying respirators may not provide adequate protection.
Hand protection: Chemical resistant gloves should be used. Gloves should be certified to an appropriate standard. Gloves should have a minimum breakthrough time that is appropriate to the duration of exposure. The breakthrough time of gloves varies according to the thickness, material and manufacturer. Gloves should be changed when breakthrough is suspected. Suitable material: nitrile rubber.
Eye protection: If eye contact is possible, use tight-fitting chemical safety goggles.
Skin and body protection: Assess the exposure and select chemical resistant clothing based on the potential for contact and the permeation / penetration characteristics of the clothing material. Wash with soap and water after removing protective clothing. Decontaminate clothing before re-use, or use disposable equipment (suits, aprons, sleeves, boots, etc.). Wear as appropriate: impervious protective suit.

9. PHYSICAL AND CHEMICAL PROPERTIES
Form: Liquid
Colour: Yellow to brown.
pH: 8-12 at 1% w/v
Flash-Point: 103°C at 757 mmHg Pensky-Martens c.c.
Density: 0.995 g/cm3 at 20°C
Water Solubility: Miscible
Dynamic Viscosity: 39.6 mPa.s at 20°C
Dynamic Viscosity: 15.2 mPa.s at 40°C
Surface Tension: 26.2 mN/m at 25°C

10. STABILITY AND REACTIVITY
Hazardous decomposition products: Combustion or thermal decomposition will evolve toxic and irritant vapours.
Hazardous reactions: None known. Hazardous polymerisation does not occur. Stable under normal conditions.

11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY (LETHAL DOSES)
Oral rat LD50: >1,500–<2,000 mg/kg
Dermal rat LD50: >4,000 mg/kg
Inhalation rat LC50: 3.2 mg/l, 4 h, derived from components

ACUTE TOXICITY (IRRITATION, SENSITISATION, ETC.)
Eye Irritation, rabbit: Irritant
Skin Irritation, rabbit: Irritant
Skin Sensitisation, guinea pig: Not sensitising.

LONG TERM TOXICITY:(Fenpropidin, difenoconazole, solvent naphtha (petroleum), highly arom.): Did not show carcinogenic, teratogenic or mutagenic effects in animal experiments

12. ECOLOGICAL INFORMATION
ELIMINATION INFORMATION (PERSISTENCE AND DEGRADABILITY)
Bioaccumulation: Difenoconazole has high potential to bioaccumulate. Fenpropidin does not bioaccumulate.
Stability in water: Difenoconazole is persistent in water. Fenpropidin is not persistent in water.
Stability in soil: Difenoconazole is very persistent in soil. Fenpropidin is moderately persistent in soil.
Mobility: Difenoconazole has low mobility in soil. Fenpropidin is immobile in soil.

ECOTOXICITY EFFECTS
Toxicity to Fish: Salmo trutta (trout), 2.6 mg/l, 96 h. Based on test results obtained with similar product.
Toxicity to Aquatic Invertebrates: EC50 Daphnia magna (water flea), 6.2 mg/l, 48 h. Based on test results obtained with similar product.
Toxicity to Algae: ErC50 Pseudokirchneriella subcapitata (green algae), 0.00056 mg/l, 72 h.

Based on test results obtained with similar product.

13. DISPOSAL CONSIDERATIONS
Product: Do not contaminate ponds, waterways or ditches with chemical or used container. Do not dispose of waste into sewer. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations.
Contaminated packaging: Empty remaining contents. Triple rinse containers. Empty containers should be taken for local recycling or waste disposal. Do not re-use empty containers

14. TRANSPORT INFORMATION
Rail/Road/Sea/Air (rid/adr/imdg-code/iata)
Class: 9
UN Number: 3082
Packaging Group: III
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (FENPROPIDIN AND DIFENOCONAZOLE AND SOLVENT NAPHTHA)
Marine pollutant: Yes

15. REGULATORY INFORMATION
Classifications/Hazard Symbols
Xn HARMFUL
N DANGEROUS FOR THE ENVIRONMENT

Risk phrases (R)
22 Harmful if swallowed.
36/37/38 Irritating to eyes, respiratory system and skin.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Safety phrases (S)
2 Keep out of the reach of children.
13 Keep away from food, drink and animal feeding stuffs.
20/21 When using do not eat, drink or smoke.
24/25 Avoid contact with skin and eyes.
26 In case of contact with eyes, rinse immediately with plenty, of water and seek medical advice.
35 This material and its container must be disposed of in a safe way.
57 Use appropriate containment to avoid environmental contamination.

Special label To avoid risks to man and the environment, comply with the instructions for use.

16. OTHER INFORMATION
Use plant protection products safely. Always read the label and product information before use.
Based upon SDS dated 22.10.2009 version 4 with local amendments.
Product approval number: MAPP 12566

Text of R phrases mentioned in Section 2:
R20/22 Harmful by inhalation and if swallowed.
R22 Harmful if swallowed.
R36/R37/38 Irritating to eyes, respiratory system and skin.
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Product Guide

Beyond the Label

Media

Social Media

FUNGICIDES