CruiserOSR, Safety Data, Seed Treatments, Syngenta Crop Protection

SEED TREATMENTS

SAFETY DATA

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY OR UNDERTAKING
Identification of the Substance or Preparation
Tradename: CRUISER OSR
Design Code: A9807C
AGI Code: 37138

Company /undertaking identification
Company Syngenta Crop Protection UK Ltd
CPC4, Capital Park, Fulbourn, Cambridge CB21 5XE
Phone (01223) 883400
Fax (01223) 882195
Website www.syngenta-crop.co.uk

2. COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENTS

thiamethoxam
CAS-NO.: 153719-23-4
EC-NO.: -
CONCENTRATION (%W/W): 24.5
HAZARD SYMBOLS: Xn, N
RISK PHRASES (R): 22, 50/53

metalaxyl-M
CAS-NO.: 70630-17-0
EC-NO.: -
CONCENTRATION (%W/W): 2.9
HAZARD SYMBOLS: Xn
RISK PHRASES (R): 22, 41

fludioxonil
CAS-NO.: 131341-86-1
EC-NO.: -
CONCENTRATION (%W/W): 0.7
HAZARD SYMBOLS: N
RISK PHRASES (R): 50/53

For the full text of the R phrases mentioned in this section, see section 16.

3. HAZARDS IDENTIFICATION
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

4. FIRST AID MEASURES
General advice: Have the product container, label or Material Safety Data Sheet with you when calling the Syngenta emergency number, a Poison Control Centre or physician, or going for treatment.
Inhalation: Remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. Keep patient warm and at rest. Call a physician or Poison Control Centre immediately.
Skin contact: Take off all contaminated clothing immediately. Wash off immediately with plenty of water. If skin irritation persists, call a physician. Wash contaminated clothing before re-use.
Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Remove contact lenses. Immediate medical attention is required.
Ingestion: If swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting.Medical advice: There is no specific antidote available. Treat symptomatically.

5. FIRE FIGHTING MEASURES
Suitable extinguishing media:
Extinguishing media – small fires: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Extinguishing media – large fires: Use alcohol-resistant foam or water spray.
Extinguishing media which must not be used for safety reasons: Do not use a solid water stream as it may scatter and spread fire.
Specific hazards during fire fighting: As the product contains combustible organic components, fire will produce dense black smoke containing hazardous products of combustion (see section 10). Exposure to decomposition products may be a hazard to health.
Special protective equipment for fire fighters: In the event of fire, wear self-contained breathing apparatus.
Further information: Do not allow run-off from fire fighting to enter drains or water courses. Cool closed containers exposed to fire with water spray.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Refer to protective measures listed in sections 7 and 8.
Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system.
Methods for cleaning up: Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local/national regulations (see section 13).
Additional advice: If the product contaminates rivers and lakes or drains inform respective authorities.

7. HANDLING AND STORAGE
HANDLING
Advice on safe handling: No special protective measures against fire required. Avoid contact with skin and eyes. When using do not eat, drink or smoke. For personal protection see section 8.

STORAGE
Requirements for storage areas and containers: No special storage conditions required. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep away from food, drink and animal feeding stuffs.
Other data: Physically and chemically stable for at least 2 years when stored in the original unopened sales container at ambient temperatures.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters

thiamethoxam
Exposure limit(s): 3 mg/m3
Value type: 8 h TWA
Source: SYNGENTA

metalaxyl-M
Exposure limit(s): 10 mg/m3
Value type: 8 h TWA
Source: SYNGENTA

fludioxonil
Exposure limit(s): 10 mg/m3
Value type: 8 h TWA
Source: SYNGENTA

ENGINEERING MEASURES
Containment and/or segregation is the most reliable technical protection measure if exposure cannot be eliminated. The extent of these protection measures depends on the actual risks in use. If airborne mists or vapours are generated, use local exhaust ventilation controls. Assess exposure and use any additional measures to keep airborne levels below any relevant exposure limit. Where necessary, seek additional occupational hygiene advice.

PERSONAL PROTECTIVE EQUIPMENT
When using this product refer to the label for details. In all other cases, use the following Personal Protective Equipment:
Protective measures: The use of technical measures should always have priority over the use of personal protective equipment. When selecting personal protective equipment, seek appropriate professional advice. Personal protective equipment should be certified to appropriate standards.
Respiratory protection: No personal respiratory protective equipment normally required. A particulate filter respirator may be necessary until effective technical measures are installed.
Hand protection: Chemical resistant gloves are not usually required. Select gloves based on the physical job requirements.
Eye protection: Eye protection is not usually required. Follow any site specific eye protection policies.
Skin and body protection: No special protective equipment required. Select skin and body protection based on the physical job requirements.

9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Viscous liquid
Colour: Light blue to dark blue
pH: 4–8 (1%), 5–7 (25°C)
Oxidising Properties: Not oxidising
Explosive Properties: Not explosive
Density: 1.148 g/cm3 20–25ºC
Dynamic Viscosity: 400–1000 mPa.s (20°C)
Dynamic Viscosity: 39.4–293 mPa.s (40°C)
Surface Tension: 49.5 mN/m (20°C)

10. STABILITY AND REACTIVITY
Hazardous decomposition products: Combustion or thermal decomposition will evolve toxic and irritant vapours.
Hazardous reactions: None known. Hazardous polymerisation does not occur. Stable under normal conditions.

11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity LD50: >3000 mg/kg (rat)
Acute Dermal Toxicity LD50: >4000 mg/kg (rat)
Skin Irritation: Non irritant (rabbit) assessment according to 93/21/EC
Eye Irritation: Non irritant (rabbit) assessment according to 93/21/EC
Sensitisation: Not sensitising (guinea pig) assessment according to 93/21/EC
Long-Term Toxicity: Liver tumours noted in mice that are not relevant to humans. Did not show reproductive toxicity effects in animal experiments. Animal testing did not show any effects on foetal development. Did not show neurotoxicity in animal experiments. This information refers to thiamethoxam. No adverse effects in humans are expected at levels below the occupational exposure limit and when the product is handled and used according to the label.

12. ECOLOGICAL INFORMATION
ELIMINATION INFORMATION (PERSISTENCE AND DEGRADABILITY)
Bioaccumulation: Thiamethoxam has low potential for bioaccumulation. Metalaxyl-M has low potential for bioaccumulation. Fludioxonil does not bioaccumulate.
Stability in water: Thiamethoxam is not persistent in water. Metalaxyl-M is not persistent in water. Fludioxonil is stable in water.
Stability in soil: Thiamethoxam is not persistent in soil. Metalaxyl-M is not persistent in soil. Fludioxonil is not persistent in soil.
Mobility: Thiamethoxam has medium mobility in soil. Metalaxyl-M has a range from low to very high mobility in soil depending on soil type. Fludioxonil has low to very high mobility in soil.

ECOTOXICITY EFFECTS
Toxicity to Fish LC50: 72 mg/l (rainbow trout; 96 h)
Toxicity to Algae ErC50: 80 mg/l (Pseudokirchneriella subcapitata (green algae), 72 h)
Toxicity to Aquatic Invertebrates EC50: 57 µg/l (Cloeon sp., 48 h, derived from active ingredient(s))
Toxicity to Aquatic Invertebrates EC50: 80 mg/l (Daphnia magna (water flea), 48 h)

13. DISPOSAL CONSIDERATIONS
Product: Do not contaminate ponds, waterways or ditches with chemical or used container. Do not dispose of waste into sewer. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations.
Contaminated packaging: Empty remaining contents. Triple rinse containers. Empty containers should be taken for local recycling or waste disposal. Do not re-use empty containers.

14. TRANSPORT INFORMATION
Rail/Road/sea/air (rid/adr/imdg-code/iata)

Class: 9
UN Number: 3082
Packaging Group: III
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (THIAMETHOXAM)
Marine pollutant: Yes

15. REGULATORY INFORMATION
Hazard symbols/Classifications
N DANGEROUS FOR THE ENVIRONMENT

Risk phrases (R)
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Safety phrases (S)
2 Keep out of the reach of children.
13 Keep away from food, drink and animal feeding stuffs.
20/21 When using do not eat, drink or smoke.
35 This material and its container must be disposed of in a safe way.
57 Use appropriate containment to avoid environmental contamination.

Special label:
To avoid risks to man and the environment, comply with the instructions for use.
Note: This preparation is classified as dangerous in accordance with Directive 1999/45/EC.

16. OTHER INFORMATION
Based on original SDS dated 01/07/2009 version 5.

Always read the label. Use pesticides safely.

Product approval number: MAPP 14496

Text of R phrases mentioned in Section 2:
R22 Harmful if swallowed.
R41 Risk of serious damage to eyes.
R50 Very toxic to aquatic organisms.
R53 May cause long-term adverse effects in the aquatic environment.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

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